(iTers News) – The future improvements in the performance of Li-Ion battery rest with technology breakthroughs in cathode materials.

SouthWest NanoTechnologies or SWeNT said today it has worked the magic using its own proprietary multi-wall carbon nanotube technology.  

Director of R&D, Ricardo Prada Silvy with SWeNT will discuss the new advancements in the SWeNT carbon nanotubes effectiveness in Li- Ion batteries at the 2012 Nanotech Conference and Expo at the Santa Clara Convention Center on June 19th.

According to Prada Silvy', its specialty multi-Wall CNTs (SMW) enable greater ease of dispersion and higher electrical conductivity than other multi-wall CNTs produced in commercial quantities.

"We're excited about the findings of our research showing that 1% wt SWeNT specialty multi-walled CNT can replace 6% wt of standard conductive carbon-P in current Li-ion battery cathode formulation, Prada Silvy explains.

"This results in improved cycle life, increased specific energy, improved performance in rate capability and lower impedance in high power electrodes. These performance benefits are attributed to an optimal control of CNT structure (morphology, higher aspect ratio (L/D), fewer number of walls, lower structural defects) and high purity levels."

The company has developed two new grades in its SMW™ line of Specialty Multi-wall CNT. These materials are used as additives that enable higher electrical conductivity in polymer compounds and improved cathode performance in Lithium Ion batteries.

The new grades, SMW200 and SMW210 have demonstrated the greatest ease of dispersions and lowest percolation threshold of any MWCNT product in multiple customer thermoplastic compound evaluations.

This enables ESD (electrostatic discharge) performance at lower filler loadings than either Carbon Black or other Multi-wall CNT, in a variety of polymers.

This low percolation threshold minimizes the degradation of physical properties of the polymer, a common problem in heavily loaded compounds, and higher conductivity at comparable loading broadens the range of applications for conductive polymer compounds.

Additionally, SMW200 compounds have been shown to have improved mechanical properties when compared to other MWCNT.

Both materials are synthesized by the CoMoCAT® method, widely recognized as producing the most consistent CNT products, and for its scalability.  Both materials disperse easily into most polymers and have the same ultra-pure, defect-free, less entangled CNT.

SMW200 is a "purified" grade, with CNT purity of 96%+ (even higher purity research grades are available upon special request).  SMW210 is an "as produced" grade, with CNT purity of 70%+, with the balance being mainly metal oxides used in the catalyst.

Because post-synthesis purification is not done for SMW210, the pricing is much lower.

SMW210 has a hybrid structure with metal-oxide particles attached to the CNT, improving dispersion still further, at a much lower cost.  In thermoplastic compounds, there is little performance difference between SMW200 and SMW210 with respect to ease of dispersion, conductivity and percolation, with most customers choosing SMW210 due to lower cost.

SMW200 has also been demonstrated as a Carbon Black replacement in Lithium Ion battery cathodes.  Very low loadings (1 wt %) of SWM200 have resulted in doubled cycle life, higher capacity, lower heat build-up and better low temperature performance.

“We have already generated a great deal of customer interest in these materials, and resulting demand is driving us to increase capacity,” says SWeNT CEO David Arthur.

"We have just shipped our first 100 kg of SMW210 for a customer's full-scale qualification trial for a high-volume conductive polymer application. Also, several Li-ion battery manufacturers are testing SMW200 now (this higher purity grade may be required for certain applications like batteries). To meet anticipated demand in 2013, SWeNT is adding capacity of multiple tonnes per month."

The company will also debut it SG65i, a new Single-Wall Carbon Nanotube (SWCNT) product with an exceptionally high concentration of semiconducting SWCNT species developed for use in printed semiconductor devices.

Its conductive and semi-conductive CNT inks for flexible printed electronics and displays are based on V2V™ Ink technology developed by alliance partner, Chasm Technologies, Inc. Using Single-Wall CNTs, these inks can be printed using commercial, high-volume printing methods and equipment, including flexographic, gravure and screen printing.

SouthWest NanoTechnologies (SWeNT) is a privately-held advanced materials company that manufactures high-quality single-wall and specialty multi-wall carbon nanotube products in a variety of forms, including powders, pastes, dispersions and inks for a wide range of applications in the electronics and composites industries.

Founded in 2001, SWeNT has established commercial-scale manufacturing operations in Norman, OK and a business & applications development center in the Boston, MA area.

 
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